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benzoate fermentation (to acetate and cyclohexane carboxylate)
|
PWY-7402
|
6-hydroxycyclohex-1-ene-1-carbonyl-CoA dehydrogenase [Had]2|acetate-CoA ligase (ADP-forming) [AcdA]2[AcdB]2|6-oxocyclohex-1-ene-1-carbonyl-CoA hydratase|cyclohexa-1,5-dienecarbonyl-CoA hydratase|cyclohex-1-ene-1-carbonyl-CoA dehydrogenase [SYN_02587]4|glutaryl-CoA dehydrogenase [GcdH]4|cyclohexane-1-carbonyl-CoA dehydrogenase|cyclohex-1-ene-1-carbonyl-CoA dehydrogenase
|
3-oxopimeloyl-CoA|benzoate|benzoyl-CoA|(S)-3-hydroxybutanoyl-CoA|cyclohex-1-ene-1-carbonyl-CoA|crotonyl-CoA|glutaryl-CoA|H2O|NAD+|acetyl-CoA|cyclohex-1,5-diene-1-carbonyl-CoA|6-oxocyclohex-1-ene-1-carbonyl-CoA|acetoacetyl-CoA|phosphate|CO2|acetate|3-hydroxypimeloyl-CoA|coenzyme A|(E)-glutaconyl-CoA|cyclohexane-1-carboxylate|diphosphate|cyclohexane-1-carbonyl-CoA|H+|NADH
|
53
|
|
C4 photosynthetic carbon assimilation cycle, NADP-ME type
|
PWY-241
|
NADP malic enzyme|β-carbonic anhydrase|phosphoenolpyruvate carboxylase|pyruvate orthophosphate dikinase|malate dehydrogenase (NADP -linked)
|
H2O|NADPH|diphosphate|(S)-malate|NADP+|phosphoenolpyruvate|hydrogen carbonate|oxaloacetate|H+|phosphate|pyruvate|CO2
|
53
|
|
L-glutamate degradation VIII (to propanoate)
|
PWY-5088
|
citramalate hydrolyase [component I][component II]|methylmalonyl-CoA carboxyltransferase [MmdA]6[PFREUD_18870]12[Bccp]12|citramalate lyase, active form
|
(R)-methylmalonyl-CoA|fumarate|acetate|NAD+|(S)-methylmalonyl-CoA|succinate|(S)-malate|mesaconate|H2O|(2S, 3S)-3-methylaspartate|oxaloacetate|(S)-citramalate|L-glutamate|H+|succinyl-CoA|ammonium|propanoate|pyruvate|NADH|propanoyl-CoA
|
53
|
|
pyruvate fermentation to propanoate I
|
P108-PWY
|
methylmalonyl-CoA mutase|methylmalonyl-CoA carboxyltransferase|propionyl-CoA:succinate CoA transferase|methylmalonyl CoA epimerase|methylmalonyl-CoA carboxyltransferase [MmdA]6[PFREUD_18870]12[Bccp]12|malate dehydrogenase
|
(R)-methylmalonyl-CoA|fumarate|H2O|NAD+|(S)-methylmalonyl-CoA|succinate|(S)-malate|oxaloacetate|H+|succinyl-CoA|propanoyl-CoA|propanoate|pyruvate|NADH
|
53
|
|
mandelate degradation to acetyl-CoA
|
PWY-6957
|
2-hydroxymuconic semialdehyde hydrolase xylF|catechol 1,2-dioxygenase|mandelate racemase|mandelate racemase mdlA|β-ketoadipate enol-lactone hydrolase|NADP+-benzaldehyde dehydrogenase|β-ketoadipate enol-lactone hydrolase [PcaD]3|4-hydroxy-2-ketovalerate aldolase|β-ketoadipyl CoA thiolase|β-ketoadipate:succinyl CoA transferase|muconolactone isomerase|benzoylformate decarboxylase|(S)-mandelate dehydrogenase|β-ketoadipate:succinyl CoA transferase [PcaI]2[PcaJ]2|4-hydroxybenzaldehyde dehydrogenase|muconate cycloisomerase|(S)-mandelate dehydrogenase mdlB
|
3-oxoadipyl-CoA|NADPH|cis,cis-muconate|(S)-mandelate|3-oxoadipate|4-hydroxy-2-oxopentanoate|H2O|benzaldehyde|NAD+|acetyl-CoA|NADP+|acetaldehyde|3,5-cyclohexadiene-1,2-diol-1-carboxylate|(2Z,4E)-2-hydroxy-6-oxohexa-2,4-dienoate|phenylglyoxylate|formate|pyruvate|CO2|benzoate|3-oxoadipate enol lactone|(R)-mandelate|succinate|oxygen|coenzyme A|muconolactone|2-oxopent-4-enoate|H+|succinyl-CoA|catechol|NADH
|
53
|
|
L-leucine degradation I
|
LEU-DEG2-PWY
|
3-methylglutaconyl-CoA hydratase|isovaleryl-CoA dehydrogenase|branched-chain α-keto acid dehydrogenase complex|3-methylcrotonyl-CoA carboxylase|3-hydroxy-3-isohexenylglutaryl-CoA lyase / hydroxymethylglutaryl-CoA lyase|methylglutaconyl-CoA hydratase, mitochondrial|branched-chain-amino-acid aminotransferase|methylcrotonyl-CoA carboxylase|2-methylacyl-CoA dehydrogenase|mitochondrial hydroxymethylglutaryl-CoA lyase|hydroxymethylglutaryl-CoA lyase
|
isovaleryl-CoA|H2O|NAD+|acetyl-CoA|L-leucine|hydrogen carbonate|CO2|3-methylcrotonyl-CoA|L-glutamate|(S)-3-hydroxy-3-methylglutaryl-CoA|4-methyl-2-oxopentanoate|H+|phosphate|3-methylglutaconyl-CoA|2-oxoglutarate|NADH|acetoacetate|coenzyme A
|
53
|
|
superpathway of menaquinol-6 biosynthesis I
|
PWY-5850
|
hexaprenyl diphosphate synthase|S-adenosyl-L-methione--menaquinol methyltransferase
|
S-adenosyl-L-methionine|2-carboxy-1,4-naphthoquinol|chorismate|all-trans-hexaprenyl diphosphate|H2O|4-(2-carboxyphenyl)-4-oxobutyryl-CoA|isochorismate|1,4-dihydroxy-2-naphthoyl-CoA|isopentenyl diphosphate|menaquinol-6|pyruvate|S-adenosyl-L-homocysteine|H+|demethylmenaquinol-6|coenzyme A|diphosphate|CO2|(1R,6R)-6-hydroxy-2-succinylcyclohexa-2,4-diene-1-carboxylate|2-succinylbenzoate|2-oxoglutarate|2-succinyl-5-enolpyruvoyl-6-hydroxy-3-cyclohexene-1-carboxylate|(2E,6E)-farnesyl diphosphate
|
52
|
|
superpathway of menaquinol-9 biosynthesis
|
PWY-5845
|
solanesyl diphosphate synthase sds1|solanesyl diphosphate synthase|1,4-dihydroxy-2-naphthoate:polyprenyltransferase|S-adenosylmethionine:2-demethylmenaquinol methyltransferase
|
S-adenosyl-L-methionine|2-carboxy-1,4-naphthoquinol|geranyl diphosphate|chorismate|H2O|4-(2-carboxyphenyl)-4-oxobutyryl-CoA|isochorismate|1,4-dihydroxy-2-naphthoyl-CoA|isopentenyl diphosphate|all-trans-nonaprenyl diphosphate|pyruvate|S-adenosyl-L-homocysteine|menaquinol-9|H+|coenzyme A|diphosphate|CO2|(1R,6R)-6-hydroxy-2-succinylcyclohexa-2,4-diene-1-carboxylate|2-succinylbenzoate|demethylmenaquinol-9|2-oxoglutarate|2-succinyl-5-enolpyruvoyl-6-hydroxy-3-cyclohexene-1-carboxylate
|
52
|
|
superpathway of 2,3-butanediol biosynthesis
|
PWY-6396
|
(R,R)-butanediol dehydrogenase [multifunctional] [BDH1]2|α-acetolactate synthase|α-acetolactate decarboxylase|diacetyl reductase / (S)-acetoin reductase [(S,S)-2,3-butanediol forming]|[(S)-acetoin forming]-diacetyl reductase [multifunctional]|L-glycol dehydrogenase|(R-acetoin forming)-(R,R)-2,3-butanediol dehydrogenase|catabolic acetolactate synthase|(R,R)-butanediol dehydrogenase [multifunctional]
|
diacetyl|NAD+|(S,S)-2,3-butanediol|(S)-2-acetolactate|CO2|(R)-acetoin|(S)-acetoin|H+|(R,R)-2,3-butanediol|(R,S)-2,3-butanediol|pyruvate|NADH
|
52
|
|
superpathway of menaquinol-10 biosynthesis
|
PWY-5896
|
decaprenyl diphosphate synthase [PDSS1]2[PDSS2]2
|
S-adenosyl-L-methionine|2-carboxy-1,4-naphthoquinol|chorismate|menaquinol-10|all-trans-decaprenyl diphosphate|H2O|4-(2-carboxyphenyl)-4-oxobutyryl-CoA|isochorismate|1,4-dihydroxy-2-naphthoyl-CoA|isopentenyl diphosphate|demethylmenaquinol-10|pyruvate|S-adenosyl-L-homocysteine|H+|coenzyme A|diphosphate|CO2|(1R,6R)-6-hydroxy-2-succinylcyclohexa-2,4-diene-1-carboxylate|2-succinylbenzoate|2-oxoglutarate|2-succinyl-5-enolpyruvoyl-6-hydroxy-3-cyclohexene-1-carboxylate|(2E,6E)-farnesyl diphosphate
|
51
|